Zinc Removal from Wastewater Using Hydrogel Modified Biochar

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In this study, hydrogel-(rice husk) biochar composite (HBC-RH) was prepared using acrylamide (AAm) as monomer, with N.N’-methylenebisacrylamide (MBA) as crosslinker, ammonium persulfate (APS) as initiator and rice husk biochar (RHB). The synthesized hydrogel-(rice husk) biochar composite was characterized for swelling capacity andthen utilized for the removal of zinc from wastewater. The optimum batch experimental conditions for this study were determined by evaluating the effect of solution pH, adsorbent dosage, adsorbate initial concentration and contact time. Langmuir isotherm best fitted the HBC-RH sorption of Zinc whereas the kinetic data were best described by pseudo second-order. The maximum monolayer sorption capacity of HBC-RH for zinc was 35.75mg/g.

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842-846

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September 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. A. Hashim, S. Mukhopadhyay, J. N. Sahu, and B. Sengupta, Remediation technologies for heavy metal contaminated groundwater., J. Environ. Manage., 92 (2011) 2355–88.

DOI: 10.1016/j.jenvman.2011.06.009

Google Scholar

[2] Z. Liu, F. -S. Zhang, Removal of lead from water using biochars prepared from hydrothermal liquefaction of biomass,J. Hazard. Mater., 167 (2009) 933–939.

DOI: 10.1016/j.jhazmat.2009.01.085

Google Scholar

[3] M. A. Barakat, E. Schmidt, Polymer-enhanced ultrafiltration process for heavy metals removal from industrial wastewater, Desalination, 256, (2010) 90–93.

DOI: 10.1016/j.desal.2010.02.008

Google Scholar

[4] N. Dali-youcef, B. Ouddane, Z. Derriche, Adsorption of zinc on natural sediment of Tafna River (Algeria).,J. Hazard. Mater., 137 (2006) 1263–70.

DOI: 10.1016/j.jhazmat.2006.03.068

Google Scholar

[5] Q. Liu, Y. Li, J. Zhang, Y. Chi, X. Ruan, J. Liu, G. Qian, Effective removal of zinc from aqueous solution by hydrocalumite, Chem. Eng. J., 175 (2011) 33–38.

DOI: 10.1016/j.cej.2011.09.022

Google Scholar

[6] F. A. Abu Al-Rub, Biosorption of Zinc on Palm Tree Leaves: Equilibrium, Kinetics, and Thermodynamics Studies, Sep. Sci. Technol., 41 (2006) 3499–3515.

DOI: 10.1080/01496390600915015

Google Scholar

[7] N. Karakoyun, S. Kubilay, N. Aktas, O. Turhan, M. Kasimoglu, S. Yilmaz, N. Sahiner, Hydrogel–Biochar composites for effective organic contaminant removal from aqueous media, Desalination, 280 (2011) 319–325.

DOI: 10.1016/j.desal.2011.07.014

Google Scholar

[8] E. -S. El-Ashtoukhy, N. K. Amin, O. Abdelwahab, Removal of lead (II) and copper (II) from aqueous solution using pomegranate peel as a new adsorbent, Desalination, 223 (2008) 162–173.

DOI: 10.1016/j.desal.2007.01.206

Google Scholar

[9] O. Ozay, S. Ekici, Y. Baran, S. Kubilay, N. Aktas, N. Sahiner, Utilization of magnetic hydrogels in the separation of toxic metal ions from aqueous environments, Desalination, 260 (2010) 57–64.

DOI: 10.1016/j.desal.2010.04.067

Google Scholar

[10] F. -M. Pellera, A. Giannis, D. Kalderis, K. Anastasiadou, R. Stegmann, J. -Y. Wang, E. Gidarakos, Adsorption of Cu(II) ions from aqueous solutions on biochars prepared from agricultural by-products., J. Environ. Manage., 96, (2012) 35–42.

DOI: 10.1016/j.jenvman.2011.10.010

Google Scholar

[11] W. Zheng, X. Li, F. Wang, Q. Yang, P. Deng, G. Zeng, Adsorption removal of cadmium and copper from aqueous solution by areca—A food waste, J. Hazard. Mater., 157 (2008) 490–495.

DOI: 10.1016/j.jhazmat.2008.01.029

Google Scholar