Effect of Shear Rate on Characteristics, Performance and Morphology of Polysulfone Blend Membranes

Article Preview

Abstract:

Rheological factor such as shear rate during membrane fabrication process has an effect on properties, structures and performance of membranes. Flat sheet asymmetric PSf/CAP blend membranes were prepared using an automatic casting machine at different shear rates in the range of 42.0 to 201.0 s-1. Results showed that increasing the shear rate from 42.0 to105 s-1 has increased the molecular orientation and thickness which then reduces the water content, porosity and pure water flux of PSf/CAP blend membranes. However, further increasing the shear rate beyond 105 s-1has resulted in an increase in the water content of PSf/CAP blend membranes.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

305-310

Citation:

Online since:

November 2014

Export:

Price:

* - Corresponding Author

[1] T.D. Kusworo, A.F. Ismail, A. Mustafa, T. Matsuura, Dependence of membrane morphology and performance on preparation conditions: The shear rate effect in membrane casting, Separation and Purification Technology. 61 (2008) 249-257.

DOI: 10.1016/j.seppur.2007.10.017

Google Scholar

[2] A.F. Ismail, M.I. Mustaffar, R.M. Illias, M.S. Abdullah, Effect of dope extrusion rate on morphology and performance of hollow fibers membrane for ultrafiltration, Separation and Purification Technology. 49 (2006) 10-19.

DOI: 10.1016/j.seppur.2005.08.001

Google Scholar

[3] A. Idris, A.F. Ismail, M. Noorhayati, S.J. Shilton, Measurement of rheologically induced molecular orientation using attenuated total reflection infrared dichroism in reverse osmosis hollow fiber cellulose acetate membranes and influence on separation performance, Journal of Membrane Science. 213(2003).

DOI: 10.1016/s0376-7388(02)00511-2

Google Scholar

[4] A.F. Ismail, A.R. Hassan, N.B. Cheer, Effect of shear rate on the performance of nanofiltration membrane for water desalination, Songklanakrin Journal of Science and Technology. 24 (2004) 879-889.

Google Scholar

[5] T.S. Chung, J.J. Qin, J. Gu, Effect of shear rate within spinneret on morphology, separation performance and mechanical properties of ultrafiltration polyethersulfone hollow fiber membranes, Chemical Engineering Science. 55 (2000) 1077-1091.

DOI: 10.1016/s0009-2509(99)00371-1

Google Scholar

[6] T.S. Chung, J.J. Qin, A. Huan, K.C. Toh, Visualization of the effect of die shear rate on the outer surface morphology of ultrafiltration membranes by AFM, Journal of Membrane Science. 196 (2002) 251-266.

DOI: 10.1016/s0376-7388(01)00609-3

Google Scholar

[7] A. Idris, A.F. Ismail, Study of shear rate influence on the performance of cellulose acetate reverse osmosis hollow fiber membranes, Journal of Membrane Science. 202 (2002) 205-215.

DOI: 10.1016/s0376-7388(01)00789-x

Google Scholar

[8] A.F. Ismail, R. Norida, W.A.W. Abdul Rahman, T. Matsuura, and S.A. Hashemifard, Preparation and characterization of hyperthin-skinned and high performances asymmetric polyethersulfone membrane for gas separation, Desalination. 273 (2011) 93-104.

DOI: 10.1016/j.desal.2010.10.015

Google Scholar

[9] M. Sivakumar, D.R. Mohan, R. Rangarajan, Studies on cellulose acetate-polysulfone ultrafiltration membranes II. Effect of additive concentration, Journal of Membrane Science. 268 (2006) 208-219.

DOI: 10.1016/j.memsci.2005.06.017

Google Scholar

[10] R.L. Machado, E.J. Arruda, C.C. Santana, S.M.A. Bueno, Evaluation of a chitosan membrane for removal of endotoxin from human IgGsolution, Process Biochemistry. 41 (2006) 2252-2257.

DOI: 10.1016/j.procbio.2006.05.015

Google Scholar

[11] A.F. Ismail, A.R. Hassan, Formation and characterization of asymmetric nanofiltration membrane: effect of shear rate and polymer concentration, Journal of Membrane Science. 270 (2006) 57-72.

DOI: 10.1016/j.memsci.2005.06.046

Google Scholar

[12] A.R. Hassan, Fabrication and Characterization of Integrally Skinned-Oriented Highly Perm-Selective Charged Asymmetric Low Pressure Nanofiltration (ALP-NF) Membranes, PhD dissertation, Universiti Malaysia Pahang, (2012).

DOI: 10.1002/jctb.2751

Google Scholar

[13] M. Mulder, Basic Principles of Membrane Technology, Kluwer Academic Publishers, The Netherlands, (1996).

Google Scholar

[14] S.A. Mckelvey, W.J. Koros, Phase separation, vitrification, and the manifestation of macrovoids in polymeric asymmetric membranes, Journal of Membrane Science. 112 (1996) 29-30.

DOI: 10.1016/0376-7388(95)00197-2

Google Scholar

[15] H. Hasbullah, S. Kumbharkar, A.F. Ismail, K. Li, Preparation of polyaniline asymmetric hollow fibre membranes and investigation towards gas separation performance, Journal of Membrane Science. 366 (2011) 116–124.

DOI: 10.1016/j.memsci.2010.09.050

Google Scholar