Electrical Generation of Dye-Sensitized Solar Cells Using Sensitizer from Rose Flower

Article Preview

Abstract:

Dye-sensitized solar cell (DSSC) is part of the thin film family that consists of a TiO2 electrode coating which acts as a photo electrode, sensitizer from dye molecules soaked in the TiO2 film, electrolyte layer and a counter electrode. This paper focuses on the usage of a sensitizer from the rose flower and will review some of the research conducted on dye sensitizers from other researcher. Rose flower also known as woody perennial of the genus Rosa, within the family Rosaceae is extracted and were used as sensitizer to fabricate dye sensitized solar cell (DSSC). The photoelectrochemical performance of Rose sensitized solar cell shows parameter of open circuit voltage, VOC, short circuit current, (ISC), fill factor (FF), solar cell efficiency (η), and peak absorbance rate as much as 0.13 V, 57.58 µA, 0.58, 0.85% and 3.5 at 550nm respectively. The photoelectrochemical performance of DSSC and the usage of natural sensitizer from Rose flower dye demonstrate good potential to be applied as a sensitizer yet detail investigations are essential in terms of its applicability for long term application.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 1008-1009)

Pages:

73-77

Citation:

Online since:

August 2014

Export:

Price:

* - Corresponding Author

[1] G. Calogero, J-H. Yum, A. Sinopoli, G. D. Marco, M. Gratzel and M. K. Nazeeruddin, Anthocyanins and betalains as light-harvesting pigments for dye-sensitized solar cells, Solar Energy 86 (2012) 1563-1575.

DOI: 10.1016/j.solener.2012.02.018

Google Scholar

[2] J. K. Tsai, W. D. Hsu, T. C. Wu, T. H. Meen and W. J. Chong, Effects of compressed TiO2 nanoparticle thin film thickness on the performance of dye-sensitized solar cells, Nanoscale Research Letters 2013, 8: 459.

DOI: 10.1186/1556-276x-8-459

Google Scholar

[3] C. G. Garcia, A. S. Polo, N. Y. M. Iha, Fruit extracts and ruthenium polypyridinic dyes for sensitization of TiO2 in photolectrochemicals solar cells, Journal of Photochemistry and Photobiology A: Chemistry 160 (2003) 87-91.

DOI: 10.1016/s1010-6030(03)00225-9

Google Scholar

[4] K. Wongcharee, V. Meeyoo and S. Chavadej, Dye-sensitized solar cell using natural Extracted from rosella and blue pea flowers, Solar Energy Materials & Solar Cells 91 (2007) 566-571.

DOI: 10.1016/j.solmat.2006.11.005

Google Scholar

[5] K. Sinha, P. D. Saha and S. Datta, Extraction of natural dye from petals of Flame of forest (Butea monosperma) flower: Process optimization using response surface methodology (RSM), Dyes and Pigments 94 (2012) 212-216.

DOI: 10.1016/j.dyepig.2012.01.008

Google Scholar

[6] M.R. Mohammadi, R.R.M. Louca, D.J. Fray and M.E. Welland, Dye-sensitized solar cells based on a single layer deposition of TiO2 from a new formulation paste and their photovoltaic performance, Solar Energy 86 (2012) 2654–2664.

DOI: 10.1016/j.solener.2012.06.005

Google Scholar

[7] J. Wu et al., Progress on the electrolytes for dye-sensitized solar cells, Pure Appl. Chem., Vol. 80, No. 11, p.2241–2258, (2008).

Google Scholar

[8] H. Chang, Y. J. Lo, Pomegranate leaves and mulberry fruit as natural sensitizers for dye-sensitized solar cells, Solar Energy 84 (2010) 1833-1837.

DOI: 10.1016/j.solener.2010.07.009

Google Scholar

[9] N.T.R.N. Kumara et al., Layered co-sensitization for enhancement of conversion efficiency of natural dye sensitized solar cells, Journal of Alloys and Compounds 581 (2013) 186–191.

DOI: 10.1016/j.jallcom.2013.07.039

Google Scholar

[10] M. S. Abdel-Latif, T. M. El-Agez, S. A. Taya, A. Y. Batniji and H. S. El-Ghamri, PlantSeeds-Based Dye-Sensitized Solar Cells, Materials Sciences and Applications, 2013, 4, 516-520.

DOI: 10.4236/msa.2013.49063

Google Scholar

[11] H. Chang, H.M. Wu, T.L. Chen, K.D. Huang, C.S. Jwo and Y. J Lo, Dye-sensitized solar cell using natural dyes extracted from spinach and ipomea, Jounal of Alloys and Compounds 495 (2010) 606-610.

DOI: 10.1016/j.jallcom.2009.10.057

Google Scholar

[12] E. M. Jin, Kyung-Hee Park, B. Jin, Je-Jung Yun and Hal-Bon Gu, Photosensitization of nanoporous TiO2 films with natural dye, Phys. Scr. T139 (2010) 014006 (5pp).

DOI: 10.1088/0031-8949/2010/t139/014006

Google Scholar

[13] H. Chang, Mu-Jung Kao, Tien-Li Chen, Chih-Hao Chen, Kun-Ching Cho and Xuan-Rong Lai, Characterization of Natural Dye Extracted from Wormwood and Purple Cabbage for Dye-Sensitized Solar Cells, International Journal of Photoenergy Volume 2013, Article ID 159502, 8 pages.

DOI: 10.1155/2013/159502

Google Scholar

[14] A. I. Babatunde, M.O. John, C. Isanbor and M.A. Olopade, The Development of Eco-friendly Photoelectrochemical solar cell Using Extract of Lonchocarpus cyanescens as a Natural Sensitizer, Advanced in Applied Science Research, 2012, 3(5): 3230-3232.

Google Scholar

[15] S. Tekerek, A. Kudret and U. Alver, Dye-sensitized solar cells fabricated with black raspberry, black carrot and rosella juice, Indian J. Phys. Vol. 85, No. 10, pp.1469-1476, October, (2011).

DOI: 10.1007/s12648-011-0166-8

Google Scholar

[16] M. Tripathi, R. Upadhyay and A. Pandey, Natural dye-based photoelectrode for improvement of solar cell performance, Ionics (2013) 19: 1179-1183.

DOI: 10.1007/s11581-012-0833-6

Google Scholar

[17] G. Calogero et al., Efficient Dye Sensitized Solar Cells Using Red Turnip and Purple Wild Sicilian Prickly Pear Fruits, Int. J. Mol. Sci. 11 (2010) 254-267.

DOI: 10.3390/ijms11010254

Google Scholar

[18] A. R. Hernandez- Martinez, M. Estevez, S. Vargas, F. Quintanilla and R. Rodriguez, New Dye-Sensitized Solar Cells Obtained from Extracted Bracts of Bougainvillea and Spectabilis Betalain Pigments by Different Purification Processes, Int. J. Mol. Sci. 2011, 12, 5565-5576.

DOI: 10.3390/ijms12095565

Google Scholar

[19] B. K. S. Perera, C. N Nupearachchi and V. P. S. Perera, Utilization of a Natural Pigments Extracted from Nilkatarolu Flowers as a sensitizer in Photoelectrochemical Solar Cells, Proceedings of the Technical Sessions, 27 (2011) 37-41.

Google Scholar

[20] M. I. Kimpa, M. Momoh, K. U. Isah, H. N. Yahya and M. M. Ndamitso, Photoelectric Characterization of Dye Sensitized Solar Cells Using Natural Dye from Pawpaw Leaf and Flame Tree Flower as Sensitizers, Materials Science and Applications 3 (2012).

DOI: 10.4236/msa.2012.35041

Google Scholar

[21] Hee-Je Kim et al., Curcumin Dye Extracted from Curcuma longa L. Used as Sensitizers for Efficient Dye-Sensitized Solar Cells, Int. J. Electrochem. Sci. 8 (2013) 8320-8328.

Google Scholar

[22] M. S. Roy, P. Balraju, M. Kumar and G.D. Sharma, Dye-sensitized solar cell based on Rose Bengal dye and nanocrystalline , Solar Energy Materials & Solar Cells 92 (2008) 909-913.

DOI: 10.1016/j.solmat.2008.02.022

Google Scholar

[23] G.R. A Kumara, S. Kaneko, M. Okuya, B. Onwona-Agyeman, A. Konno and K. Tennakone, Shiso leaf pigments for dye-sensitized solid-state solar cell, Solar Energy Materials & Solar Cells 90 (2006) 1220-1226.

DOI: 10.1016/j.solmat.2005.07.007

Google Scholar

[24] K.V. Hemalatha, S.N. Karthick, C. Justin Raj, N, -Y. Hong, S. -K. Kim and H. -J. Kim, Performance of Kerria japonica and Rosa chinensis flower dyes as sensitizers for dye- sensitized solar cells, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 96 (2012).

DOI: 10.1016/j.saa.2012.05.027

Google Scholar

[25] N. Gomesh, R. Syafinar, M. Irwanto, Y.M. Yusoff, U. hashim, N. Mariun, Solar cell using sensitizer extracted from organic substances, 2014 IEEE 8th International Power Engineering and Optimization Conference (PEOCO 2014), pp.543-545.

DOI: 10.1109/peoco.2014.6814488

Google Scholar