Mechanical and Morphological Properties of Tropical Wood Polymer Nanocomposite (WPNC)

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A novel route to wood modification by impregnation of nanoclay combined with phenol formaldehyde (PF) resin is developed in this study. Wood polymer nanocomposites (WPNCs) were prepared from several tropical wood species by impregnating the woods with PF/nanoclay formulations. The vacuum-pressure method was used to impregnate the samples with PF/nanoclay prepolymer mixture. The formation of wood polymer nanocomposites and the location of impregnated materials inside wood were confirmed through SEM image and XRD pattern respectively. The PF/nanoclay loading achievable was found to be dependent on the properties of wood species. Low loading was observed for the high density wood species. Mechanical strength of fabricated WPNCs in terms of modulus of elasticity (MOE) was found to be significantly improved. Furthermore, morphological properties of raw wood and WPNC samples were evaluated by scanning electron microscopy (SEM) and XRD analysis and a change in morphological properties was also observed for WPNC.

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200-205

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March 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

[1] L.D. Vetter, M. Stevens, J.V. Acker, Fungal decay resistance and durability of organosilicon-treated wood, Int. Biodet. & Biodeg. 63 (2009) 130-134.

DOI: 10.1016/j.ibiod.2008.08.002

Google Scholar

[2] M.K. Yalinkilic, K. Tsunoda, M. Takahashi, E.D. Gezer, W. Dwianto, H. Nemoto, Enhancement of biological and physical properties of wood by boric acid-vinyl monomer combination treatment, Holzforschung. 52(6) (1998) 667-672.

DOI: 10.1515/hfsg.1998.52.6.667

Google Scholar

[3] S. Kumar, Chemical modification of wood, Wood Fib. Sci. 26 (1994) 270-280.

Google Scholar

[4] M.S. Islam, S. Hamdan, M.R. Rahman, I. Jusoh, A.S. Ahmed, The effect of crosslinker on mechanical and morphological properties of tropical wood material composites, Mat. & Design. 32 (2011) 2221-2227.

DOI: 10.1016/j.matdes.2010.11.026

Google Scholar

[5] R. Bergman, R.E. Ibach, C. LaPasha, J. Denig, Evaluating physical properties changes for small diameter plantation-grown southern pine after in situ polymerization of an acrylic monomer, Forest Prod. J. 59 (10) (2009) 64-71.

DOI: 10.13073/0015-7473-59.10.64

Google Scholar

[6] U.C. Yildiz, S. Yildiz, E.D. Gezer, Mechanical properties and decay resistance of wood polymer composites prepared from fast growing species in Turkey, Bioresource Technol. 96 (2005) 1003-1011.

DOI: 10.1016/j.biortech.2004.09.010

Google Scholar

[7] R.M. Rowell. Chemical modification of wood: In handbook of wood chemistry and wood composite. Rowell, R.M. (ed. ) Taylor and Francis, (2005).

Google Scholar

[8] M.S. Islam, S. Hamdan, M.R. Rahman, I. Jusoh, N.F. Ibrahim, Dynamic Young's modulus and dimensional stability of batai tropical wood impregnated with polyvinyl alcohol, J. Sci. Res. 2(2) (2010) 227.

DOI: 10.3329/jsr.v2i2.2729

Google Scholar

[9] P. Larsson, R. Simonson, A study of strength, hardness and deformation of cetylated Scandinavian softwood, Holz Roh Werkst. 52 (1994) 83-86.

DOI: 10.1007/bf02615470

Google Scholar

[10] X. Cai, B. Riedl, S.Y. Zhang, H. Wan, The impact of interphase between wood, melamine-urea-formaldehyde and layered silicate on the performance of wood polymer nanocomposites, Holzforschung 61 (2007) 148-154.

DOI: 10.1515/hf.2007.027

Google Scholar

[11] X. Cai, B. Riedl, S.Y. Zhang, H. Wan, Effects of nanofillers on water resistance and dimensional stability of solid wood modified by melamine-urea-formaldehyde resin, Wood Fib. Sci. 39(2) (2007) 307-318.

Google Scholar

[12] P. Bordes, E. Pollet, L. Averous, Nano-biocomposites : Biodegradable polyester/nanoclay system. Prog. in Polym. Sci. 34 (2009) 125-155.

DOI: 10.1016/j.progpolymsci.2008.10.002

Google Scholar

[13] S.S. Ray, M. Okamoto, Polymer/layered silicate nano-compoistes: a review from preparation to processing, Prog. Polym. Sci. 28 (2003) 1539-1641.

DOI: 10.1016/j.progpolymsci.2003.08.002

Google Scholar

[14] M.G. S Yap, L.H.L. Chia, S.H. Teoh, Wood polymer composites from some tropical hardwood, J. Wood Chem. Technol. 10(1) (1990) 1-19.

Google Scholar

[15] M. Deka, C.M. Saikia, Chemical modification of wood with thermosetting resin: Effect on dimensional stability and strength property, Bioresource Technol. 73 (2000) 179-181.

DOI: 10.1016/s0960-8524(99)00167-4

Google Scholar

[16] N.E. Zafeiropoulos, D.R. Williams, C.A. Baillie, F.L. Matthews, Engineering and characterisation of the interface in flax fibre/Polypropylene, Compos. Part A. 33(8) (2002) 1083-1093.

DOI: 10.1016/s1359-835x(02)00082-9

Google Scholar

[17] M.A. Khan, K.M.I. Ali, W. Wang, Electrical properties and X-ray diffraction of wood and wood plastic composite (WPC), Radiat. Phys. Chem. 38(3) (1991) 303-306.

DOI: 10.1016/1359-0197(91)90097-l

Google Scholar