Modeling of Oligomerization of C9 Fraction of Petrol Pyrolysis

A.A. Lyapkov; E.I. Ionova; V.G. Bondaletov; A.N. Pestryakov

doi:10.4028/www.scientific.net/AMR.772.292

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 772Modeling of Oligomerization of C9 Fraction of...

Modeling of Oligomerization of C₉ Fraction of Petrol Pyrolysis

Abstract:

Process of terpolymerization of basic unsaturated components of liquid products of pyrolysis of straight-run gasoline in toluene solution has been studied as model of oligomerization of C₉ fraction under the action of catalytic system TiCl₄Al (C₂H₅)₂Cl. Relative reactivity of styrene, indene and dicyclopentadiene (80-85 % from total amount of monomers) was established. On the basis of data of adiabatic thermometry, IR and ¹H NMR spectroscopy we revealed possibilityto synthesize polymeric and oligomeric products.These products basically correspondto the industrial petropolymericresinsobtained from C₉fraction.

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Periodical:

Advanced Materials Research (Volume 772)

Pages:

292-296

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.772.292

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Online since:

September 2013

Authors:

A.A. Lyapkov, E.I. Ionova, V.G. Bondaletov, A.N. Pestryakov

Keywords:

Catalytic Oligomerization, Dicyclopentadiene, Indene, Liquid Products of Pyrolysis, Petropolymeric Resins, Styrene

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