A Study on the Effect of Modified Electrolyte to the Formation of AAO Membrane in Anodising Process

Article Preview

Abstract:

The formation of anodic aluminium oxide (AAO) membrane in anodising process has been studied. The anodising process was done in two different type of electrolyte which are single phosphoric acid and a mixture of phosphoric acid and acetic acid. This study was done to determine the influence of this mixed electrolyte toward the formation of AAO membrane. The anodising voltage was control from 90V to 130V while concentration, time, and temperature were kept constant at 1M, 60 minute and 15°C respectively. The characterisation of the AAO membrane was done by using scanning electron microscopy (SEM). The results of this study confirm that the addition of organic acid in the acidic based electrolyte resulted to the larger pores size of AAO membrane.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

223-227

Citation:

Online since:

September 2013

Export:

Price:

[1] Ali Eftekhari, (2008). Nanostructured Materials in Electrochemistry, Wiley-VCH, Weinheim.

Google Scholar

[2] Nagaura, T., Takeuchi, F., & Inoue, S. (2008). Fabrication and structural control of anodic alumina films with inverted cone porous structure using multi-step anodizing. Electrochimica Acta, 53(5), 2109-2114.

DOI: 10.1016/j.electacta.2007.09.016

Google Scholar

[3] Su, S. H., Li, C. S., Zhang, F. B., & Yokoyama, M. (2008). Characterization of anodic aluminium oxide pores fabricated on aluminium templates. Superlattices and Microstructures, 44(4-5), 514-519.

DOI: 10.1016/j.spmi.2008.02.001

Google Scholar

[4] H. Wang and H.W. Wang, (2006). Analysis On Porous Aluminum Anodic Oxide Film Formed In Re–OA–H3PO4 Solution, J. Materials Chemistry and Physics, 97, p.213–218.

DOI: 10.1016/j.matchemphys.2005.03.061

Google Scholar

[5] Allen Bai a, Chi-Chang Hub, Yong-Feng Yang and Chi-Cheng Lin, (2007). Pore Diameter Control Of Anodic Aluminum Oxide With Ordered Array Of Nanopores, Journal of Electrochimica Acta, 53, p.2258–2264

DOI: 10.1016/j.electacta.2007.09.039

Google Scholar

[6] Ma Song-Jiang, Luo Peng, Zhou Hai-Hui, Fu Chao-peng and Kuang Ya-Fei, (2008). Preparation Of Anodic Films On 2024 Aluminum Alloy In Boric Acid-Containing Mixed Electrolyte, Journal of Trans. Nonferrus Met. Soc. China, 18, pp.825-830

DOI: 10.1016/s1003-6326(08)60143-0

Google Scholar

[7] Wang, H., & Wang, H. (2005). Thick and macroporous anodic alumina membranes for self-lubricating surface composites. Applied Surface Science, 249(1-4), 151-156.

DOI: 10.1016/j.apsusc.2004.11.058

Google Scholar

[8] Froimovitch, A. (2006). Nanoporous and Nanostructured Aluminium and Titanium Oxide Thin Films. Carleton University, Canada.

DOI: 10.22215/etd/2007-10656

Google Scholar

[9] Rajagopal, C., & Vasu, K. I. (2000). Conversion Coatings A Reference for Phosphating, Chromating and Anodizing Processes. New Delhi: McGraw-Hill

Google Scholar

[10] Vrublevsky, I., Parkoun, V., & Schreckenbach, J. (2005). Analysis of porous oxide film growth on aluminum in phosphoric acid using re-anodizing technique. Applied Surface Science, 242(3-4), 333-338.

DOI: 10.1016/j.apsusc.2004.08.034

Google Scholar

[11] Mazhar, A. A., Heakal, F. E.-T., & Awad, K. M. (1990). Some formation factors affecting the dissolution behaviour of anodic oxide films on aluminum in H3PO4. Thin Solid Films, 192(2), 193-199.

DOI: 10.1016/0040-6090(90)90064-k

Google Scholar

[12] A.O. Araoyinbo, A.F.M. Noor, S. Sreekantan and A. Aziz (2010). Voltage Effect On Electrochemical Anodization Of Aluminum At Ambient Temperature. International Journal of Mechanical and Materials Engineering (IJMME), Vol. 5, No. 1, 53-58.

Google Scholar

[13] Alaba O. Araoyinbo, Azmi Rahmat, Mohd Nazree Derman and Khairel Rafezi Ahmad (2012). Room temperature anodization of aluminum and the effect of the electrochemical cell in the formation of porous alumina films from acid and alkaline electrolytes. Journal of Adv. Mat. Lett. 2012, 3(4), 273-278.

DOI: 10.5185/amlett.2012.2323

Google Scholar